Hopefully you haven't run brew cleanup postgresql yet. brew info gives all the relevant info, including if you still have the previous version and the fact you willmight need to run pg_upgrade (shortened output below).
This will tell you what version your db is on: cat /usr/local/var/postgres/PG_VERSION
If you didn't mean to upgrade to PostgreSQL 10.1, and assuming your previous version is 9.6.6, this could be enough: brew switch postgresql 9.6.6
If you need to reinstall an older version, this could work: https://stackoverflow.com/a/9832084/279726
It looks like the data directory is /usr/local/var/postgres by default (as I haven't changed mine), see last line of output below.
$ brew info postgresql
postgresql: stable 10.1 (bottled), HEAD
[...]
==> Caveats
To migrate existing data from a previous major version of PostgreSQL, see:
https://www.postgresql.org/docs/10/static/upgrading.html
You will need your previous PostgreSQL installation from brew to perform
`pg_upgrade` or `pg_dumpall` depending on your upgrade method.
Do not run `brew cleanup postgresql` until you have performed the migration.
To have launchd start postgresql now and restart at login:
brew services start postgresql
Or, if you don't want/need a background service you can just run:
pg_ctl -D /usr/local/var/postgres start
$
But if you do want to use 10.1, basically you could run something like this, still assuming you were running 9.6.6 before (change directory name based on your actual previous PostgreSQL version). Run one command at a time and check the output before proceeding with the next:
mv -i /usr/local/var/postgres /usr/local/var/postgres96
mkdir /usr/local/var/postgres
pg_upgrade -b /usr/local/Cellar/postgresql/9.6.6/bin -B /usr/local/Cellar/postgresql/10.1/bin -d /usr/local/var/postgres96 -D /usr/local/var/postgres
See here for details: https://www.postgresql.org/docs/10/static/pgupgrade.html
********************************************************
* PLEASE MAKE BACKUPS BEFORE DOING ANY OF THE ABOVE!!! *
********************************************************
The funny thing is, if I try to install the latest PostgreSQL I get:
$ brew install postgresql
Error: postgresql 9.5.5 is already installed
To upgrade to 10.1, run `brew upgrade postgresql`
So I'm not sure how you got from 9.6.x to 10.1 without seeing that message...