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Cobalt(II) phosphate

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Cobalt(II) phosphate
Names
Other names
  • Cobalt violet
  • Cobalt(II) phosphate
  • Cobalt orthophosphate
  • Pigment Violet 14
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.309 Edit this at Wikidata
EC Number
  • 236-655-6
UNII
  • InChI=1S/3Co.2H3O4P/c;;;2*1-5(2,3)4/h;;;2*(H3,1,2,3,4)/q3*+2;;/p-6
    Key: ZBDSFTZNNQNSQM-UHFFFAOYSA-H
  • InChI=1/3Co.2H3O4P/c;;;2*1-5(2,3)4/h;;;2*(H3,1,2,3,4)/q3*+2;;/p-6
    Key: ZBDSFTZNNQNSQM-CYFPFDDLAU
  • [O-]P(=O)([O-])[O-].[O-]P(=O)([O-])[O-].[Co+2].[Co+2].[Co+2]
Properties
Co3(PO4)2
Molar mass 366.74231 g/mol
Appearance violet solid
Density 3.81 g/cm3
Melting point 1,160 °C (2,120 °F; 1,430 K)
insoluble
2.05×10−35[1]
28,110.0·10−6 cm3/mol
1.7
Hazards
GHS labelling:[2]
GHS07: Exclamation mark
Warning
H302, H315, H317, H319, H335
P261, P264, P264+P265, P270, P271, P272, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P333+P317, P337+P317, P362+P364, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Cobalt phosphate is the inorganic compound with the formula Co3(PO4)2. It is a violet solid that is insoluble in water.

Structure

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According to X-ray crystallography, the anhydrous Co3(PO4)2 consists of discrete phosphate (PO3−
4) anions that link Co2+
 centres. The cobalt ions occupy both octahedral (six-coordinate) and pentacoordinate sites in a 1:2 ratio.[3][4]

Preparation

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The tetrahydrate Co3(PO4)2•4H2O precipitates as a solid upon mixing aqueous solutions of cobalt(II) and phosphate salts.[5][6] Upon heating, the tetrahydrate converts to the anhydrous material.

Uses

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Thin films of this material are water oxidation catalysts.[7]

It is also a commercial inorganic pigment known as cobalt violet (PV14).[8]

A swatch of cobalt violet, popular among the French impressionists.

See also

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References

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  1. ^ John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99th ed.). CRC Press. pp. 5–188. ISBN 978-1138561632.
  2. ^ PubChem. "Cobaltous phosphate". pubchem.ncbi.nlm.nih.gov. Retrieved 2026-03-11.
  3. ^ Anderson, J. B.; Kostiner, E.; Miller, M. C.; Rea, J. R. (1975). "Crystal structure of cobalt orthophosphate Co3(PO4)2". Journal of Solid State Chemistry. 14 (4): 372–377. Bibcode:1975JSSCh..14..372A. doi:10.1016/0022-4596(75)90058-4.
  4. ^ Nord, A. G.; Stefanidis, T. (1983). "Structure refinements of Co3(PO4)2. A Note on the Reliability of Powder Diffraction Studies". Acta Chemica Scandinavica A. 37: 715–721. doi:10.3891/acta.chem.scand.37a-0715.
  5. ^ Donaldson, John Dallas; Beyersmann, Detmar (2005). "Cobalt and Cobalt Compounds". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a07_281.pub2. ISBN 9783527303854.
  6. ^ Sankar, Selvasundarasekar Sam; Rathishkumar, Arumugam; Geetha, Kathiresan; Kundu, Subrata (2020-10-15). "A Simple Route for the Synthesis of Cobalt Phosphate Nanoparticles for Electrocatalytic Water Oxidation in Alkaline Medium". Energy & Fuels. 34 (10): 12891–12899. doi:10.1021/acs.energyfuels.0c02809. ISSN 0887-0624. S2CID 224960926.
  7. ^ Matthew W. Kanan; Yogesh Surendranatha; Daniel G. Nocera (2009). "Cobalt–phosphate oxygen-evolving Compound". Chem. Soc. Rev. 38 (1): 109–114. doi:10.1039/B802885K. PMID 19088970.
  8. ^ Hugo Müller, Wolfgang Müller, Manfred Wehner, Heike Liewald "Artists' Colors" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. doi:10.1002/14356007.a03_143.pub2
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