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. 2005 Oct 7:(37):4723-5.
doi: 10.1039/b509188h. Epub 2005 Aug 23.

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Xile Hu  1 , Brandi M Cossairt, Bruce S Brunschwig, Nathan S Lewis, Jonas C Peters
Affiliations

Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Xile Hu et al. Chem Commun (Camb). .

Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as -0.28 V vs. SCE.

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