According to the error message, you have a "*" in front of the "Server" keyword in your connection string. I suspect the connection string you pasted in your question is not the same connection string that your web app is using.
Here is some example code which produces the exact same error message. Notice the "*" character that I added:
var connString = "*server=tcp:northwndtestserver,1433;Database=HealthCureSystem;User ID=bl;Password=mygyhcg89;Encrypt=True;TrustServerCertificate=False;Connection Timeout=30"
var cn = new SqlConnection(connString);
And here is the error message, which matches yours:
System.ArgumentException: Keyword not supported: '*server'.
at System.Data.Common.DbConnectionOptions.ParseInternal(Hashtable parsetable, String connectionString, Boolean buildChain, Hashtable synonyms, Boolean firstKey)
at System.Data.Common.DbConnectionOptions..ctor(String connectionString, Hashtable synonyms, Boolean useOdbcRules)
at System.Data.SqlClient.SqlConnectionString..ctor(String connectionString)
at System.Data.SqlClient.SqlConnectionFactory.CreateConnectionOptions(String connectionString, DbConnectionOptions previous)
at System.Data.ProviderBase.DbConnectionFactory.GetConnectionPoolGroup(DbConnectionPoolKey key, DbConnectionPoolGroupOptions poolOptions, DbConnectionOptions& userConnectionOptions)
at System.Data.SqlClient.SqlConnection.ConnectionString_Set(DbConnectionPoolKey key)
at System.Data.SqlClient.SqlConnection.set_ConnectionString(String value)
at System.Data.SqlClient.SqlConnection..ctor(String connectionString, SqlCredential credential)
at System.Data.SqlClient.SqlConnection..ctor(String connectionString)