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As an exercise in chemistry, I decided to observe the kinetics of the decay of thiosulfate ions in an acidic medium. As far as I am aware, it is a very well known exercise among chemists.

I found a paper in which the author uses a sodium thiosulfate solution with a concentration of 0.25 mol/L and sulfuric acid with a concentration of 0.25 mol/L. I would like to know if it is okay to use hydrochloric acid with a concentration of 0.50 mol/L, instead of sulfuric acid? In other words, can I expect the same turbidity time of the aqueous solution as the author?

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  • $\begingroup$ Not exactly, 2nd proton isn't as acidic in H2SO4, and there's a bigger issue - it an be reduced. $\endgroup$ Commented Apr 17, 2025 at 11:35
  • $\begingroup$ Considering different ionic power and just partial dissociation of HSO4^-, leading to different H+(aq) activity, the time values will be just similar/comparable. $\endgroup$ Commented Apr 17, 2025 at 11:35
  • $\begingroup$ related chemistry.stackexchange.com/questions/66141/… chemistry.stackexchange.com/questions/74021/… $\endgroup$ Commented Apr 17, 2025 at 15:45

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