Newest Questions
47,367 questions
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How does DMSO facilitate transdermal toxicity of sodium azide, and what are the key solubility, compatibility, and permeation kinetics involved? [closed]
Background
DMSO is a skin penetration enhancer. Sodium azide (NaN₃) is toxic. When mixed, DMSO can carry azide through skin without chemical change. I want to understand the hazards.
Questions
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3
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1
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374
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How does one decompose hydrogen peroxide in a nitric acid solution so that it can be disposed of with out generating oxygen gas later?
I am removing high phosphorous (5~10%) nickel electroless plating from alumina circuit boards using 125 ml concentrated nitric acid to 250 ml water and 60 ml 35% hydrogen peroxide, generally following ...
1
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0
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62
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Can we determine pressure downstream by following the streams from upstream?
I am working on an assignment for university where I have to design a process to produce a certain product. The stream that initially enters my reactor actually is a mixture of three streams: a fresh ...
6
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3
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495
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Deriving helium atom wavefunction
I have made a effort to recalculate the wavefunction of the electrons of the He atom. Schrödinger’s time-independent equation in natural units for the He atom is
$$\left(-\frac 12\vec\nabla^2_{r_1} - \...
6
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2
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96
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Difference between molecular geometry and shape in VSEPR
I was recently studying chemical bonding for the first time where I was introduced to molecular geometry and molecular shape. What is the exact difference between these to terms used in VSEPR?
For ...
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1
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41
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Is the branching of alkanes the only thing that affects boiling point? [closed]
I found data on the boiling point of the isomers of heptane and hexane. For example I am interested how to determinate branching of 2-methilhexane and 3-methilhexane, which of them would and why would ...
1
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0
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61
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How does the severity of chemical leaching from PET bottles change over continued reuse?
Soft drinks are typically sold in translucent plastic bottles - whether smaller 0.5L, larger 1.5L or 2.0L, or other sizes. In this question, let's focus on bottles made from PET (poly(ethylene ...
0
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1
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Could electrons in Rutherford's Solar system model of the atom follow several different orbits?
I recently took a test for a lab class I have and one of the questions was:
In the Classical Solar System model, what was the atom like?
a: there is a nucleus where the proton resides
b: There are ...
1
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0
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70
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Can we fix both temperature and pressure in a flash tank?
I am working on a project for a university assignment, and part of this requires me to model a flash tank in Python.
I am wondering if it is a reasonable assumption that we can fix both the ...
0
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Prebiotic Life - Mechanistic approach [duplicate]
There is a problem sequence in this year's IChO preparatory, based on the synthesis of ribonucleic acids in the prebiotic earth suggested by Powner et al.:
(Adapted from Nature)
Apparently the ...
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Ethyl Lactate for fire breathing [closed]
I have an interesting question for you all! I'm interested in your personal opinion of using Ethyl Lactate as a fire breathing fluid. Most fire breathers will use ultra pure lamp oil, which is not ...
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0
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How many grams of CO2 is in a can of Solo (375ml)? [duplicate]
This may be for my Australians out there. There is a popular drink in Australia known as Solo. It is a lemonade drink that is lightly carbonated. I am trying to recreate it with my limited chemistry ...
2
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1
answer
60
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What are the statistical thresholds for rejecting the y-intercept in linear regression models during method validation
In method validation and linearity studies, a y-intercept of zero is the ideal. However, in practice, some deviation is expected. Beyond the qualitative preference for a 'small' intercept, are there ...
4
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1
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247
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Mechanism of addition of glyceraldehyde to oxazole
This was originally from a paper regarding prebiotic chemistry by Powner and Suterland (doi:10.1098/rstb.2011.0134, complete reference below the question):
I am pretty interested in the mechanism of ...
2
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1
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175
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Why not add iodine in the test tube while studying effects of temperature on starch amylase?
The procedure in the textbook is like below:
Heat the test tubes holding starch solution and amylase solution to the desired temperature.
Mix them.
Every minute transfer a drop of the mixture to a ...