Naimark Duality Theorem: Let $(\varphi_{i})_{i \in I} \subset \mathcal H$. Then $(\varphi_{i})_{i \in I}$ is a frame iff $\exists$ a Hilbert space $\mathcal K \supset \mathcal H$ and a Riesz Basis $(\psi_{i})_{i \in I}$ for $\mathcal K$ s.t. $\mathcal P_{\mathcal H}\psi_i = \varphi_i$ for all $i \in I$ where $\mathcal P_{\mathcal H}$ is as usual the orthogonal projection of $\mathcal K$ onto $\mathcal H$.
Concerning $\Rightarrow$, the proof starts as follows: Since $(\varphi_{i})_{i \in I}$ is a frame, there is a result that states that the analysis operator $T$ maps $\mathcal H$ bijectively onto a closed subset of $\ell_2(I)$ which we denote by $\mathcal M$. Consider $V: \mathcal M \to \mathcal H, Vc := T^*c$, where $T^*$ the synthesis operator (and adjoint of $T$).
Now let $(e_{i})_{i \in I}$ be the standard orthonormal basis. Since $\ker T^*= \ker P_{\mathcal M} = \mathcal M^⊥$, $V \mathcal P_{\mathcal M} e_i =T^{*} P_{\mathcal M} e_i = T^*e_i = \varphi_i$.
So basically, $e_i$ lies in $\mathcal M$ for all $i \in I$ and $\mathcal M$ is a closed subset of $\ell_2(I)$, then I would follow that $\mathcal M = \ell_2(I)$? That wouldn't make sense.