When you're treating matrices as objects in a vector space, instead of as representations of a transformation, then it's often useful to think of them as vectors with components.
A 2x2 matrix has four components, a 3x3 matrix has 9 components, a 4x4 matrix has 16 components, and so on.
Every 2x2 matrix can be written uniquely as:
$$\begin{bmatrix}a & b \\ c & d\end{bmatrix} = a\begin{bmatrix}1 & 0 \\ 0 &0 \end{bmatrix} + b\begin{bmatrix}0 & 1 \\ 0 &0 \end{bmatrix} + c\begin{bmatrix}0 & 0 \\ 1 &0 \end{bmatrix}+d\begin{bmatrix}0 & 0 \\ 0 &1 \end{bmatrix}$$
In other words, these four matrices on the right hand side form a basis for the space.
Because we're treating these matrices as objects in a vector space, you are free to write them as vectors if you like.
$$\begin{bmatrix}a & b \\ c & d\end{bmatrix} \leadsto \begin{bmatrix}a \\ b\\ c\\d\end{bmatrix}$$
Written in this form, transposition is the transformation:
$$T : \begin{bmatrix}a \\ b\\ c\\d\end{bmatrix} \mapsto \begin{bmatrix}a \\ c\\ b\\d\end{bmatrix}$$
which you can write in matrix form as:
$$\underbrace{\begin{bmatrix}1 & 0 & 0 & 0\\ 0 & 0 & 1 & 0 \\ 0 & 1& 0 & 0\\ 0&0&0&1\end{bmatrix}}_T\begin{bmatrix}a \\ b\\ c\\d\end{bmatrix} = \begin{bmatrix}a \\ c\\ b\\d\end{bmatrix}$$
and you can do the rest.
Of course, you can also get some intuition about transposition using intuition about eigenvectors, without relying on specific components.
If a linear transformation scales an object by a factor of $\lambda\neq 0$, then that object is an eigenvector with eigenvalue $\lambda$. (As a special case, if a linear transformation has no effect on an object, it's an eigenvector with eigenvalue $\lambda=1$.)
Let's exclude the zero matrix from consideration in everything that follows. There are three kinds of matrices that are unaffected by transposition $T$:
$$\begin{bmatrix}a & 0\\ 0 & 0\end{bmatrix}, \begin{bmatrix}0 & 0\\ 0 & b\end{bmatrix},
\begin{bmatrix}0 & c\\ c & 0\end{bmatrix}$$
As a result, these are eigenvectors of $T$, and they all have eigenvalue 1. The linear combinations of these matrices form a three dimensional space of matrices that are all eigenvectors with eigenvalue 1:
$$\begin{bmatrix}a & c \\ c & d\end{bmatrix}\qquad \forall a, b, c$$