While, as others have already pointed out, using glass-blowing techniques on steel is impractical to say the least (not to mention the fact that it'll radiate nearly 300 kilowatts per square meter in infrared radiation when molten) and that bulk metallic glasses are somewhat of an exotic medium.
However, that's not to say that there is no application for inflatable metals, may I introduce you to the main intake fan blades of the Rolls Royce Trent 1000 jet engine. I'll let Rolls Royce explain...


It's a kind of middle ground between blow molding and stamping, titanium panels come in as a stack of flat sheets with a special bonding pattern which are them inflated like a balloon inside a mold. Probably as close as you're realistically going to get to an inflatable metal ship.
You could make the outer shell of your space ship really strong by using large pre-fab panels which both frees up the inside (less internal bracing needed) and as a bonus, the finished structure closely resembles a whipple shield which gets you some extra protection from asteroids and hyper-velocity balistic projectiles.

Whipple shields work by having multiple layers to break up and spread out impactors. After all, a cloud of sand is easier to stop than a bullet with the same total mass and speed.