Based on this Evil Ward, it seems to have two main parts to it:
- No one can harbor ill intent within their minds
- Any action that might harm another to your own benefit would seem to you as repulsive
That second part, about harming another, is the dangerous part and will be the biggest determination of what triggers the revulsion.
Also, just because an idea is repulsive, does not mean that somebody won't do it anyways if they are desperate enough, or have enough ill intent to overpower the revulsion.
The Case for Police
Would there be police? Short answer, yes.
However, they are likely not be as well armed as some police forces of the world. Taking the decision to end a life, even in pursuit of your duties is harming another for your own benefit and said officer almost certainly has ill intent towards the person they have decided to strike down. Your police force will know this and either have something to bypass the spell, or more likely have to use their words more than their weapons.
The crime profile might be different in this city, but there are still disputes that would require mediation and enforcement -- noise complaints, domestic arguments, enforcement of court orders, etc. There will still be violence and thefts, but they will be lessened by the spell -- hopefully.
Possibly, given the fact that the Anti-Evil Spell curtails a lot of crime, a police force in this city might be more public service oriented and have a better overall reputation -- a trusted point of first contact for those that need help in general. These are the people that can be the launching point to get in touch with other services.
But yes, there will still be some manner of law enforcement organization. The Anti-Evil spell curtails evil, not lawlessness.
Plus, this does not get into any other government organization that enforces specific sets of rules. You know, like the group that enforces governmental order by the invocation and maintenance of the large Anti-Evil spell over the city.
On Anti-Evil
Of note is that the two halves of your statement are not necessarily mutually exclusive. You can harm somebody without harbouring ill intent against them.
For an extreme example, somebody can fell no ill intent in their murder of another because they lack the necessary mindset to feel that intent. As the murder doesn't benefit them in any way, it shouldn't trigger the repulsion of the spell on that count either.
Depending on the exact nature of the Anti-Evil spell, no surgeon could practice in the city as while they have no ill intent, technically they are doing harm in their attempt to heal (surgery) for their own benefit (a paycheck).
While I don't know the parameters of the Anti-Evil spell, it could be anything from a mild nuisance in one's life to wildly defining one's existence.
But be aware that Evil does not always mean lawless nor Good lawful. It's an interesting philosophical debate that I am absolutely unqualified to have as I did not study this in school.
Societal Change
Unstated in the question, but something else to consider is how this Anti-Evil ward would affect the city's operation itself. Ill intent and harm to another for self benefit are vague -- perhaps intentionally so -- but it does open up questions about what exactly it takes to trigger the spell and how the city, and the society born from it have to change in order to live by the dictates of the spell.
Perhaps once the effects on the society are determined, it becomes easier to figure out what kind of law enforcement forces are needed.