A better equality plots.
Expression for eq and r are taken from OP code and then they are used to make equations in a slightly different form. The equations are used in ContourPlot3D instead of RegionPlot3D used in OP.
eq = v == (-a^2 + 2 a c + a^2 c - c^2 - c^3)/(a c - c^2 - c^3);
r = Root[a^2 - a c - a^2 c + 2 a c^2 -
c^3 + (-a^2 + a^3 + a c + 3 a^2 c - a^3 c - 5 a c^2 +
2 c^3) #1 + (2 a^3 - 5 a^2 c - a^3 c + 4 a c^2 + 2 a^2 c^2 -
c^3 - a c^3) #1^2 + (-a^3 + 2 a^2 c + a^3 c - a c^2 -
2 a^2 c^2 + a c^3) #1^3 &, 3];
nr = Root[r[[1]]@(1/x) // Factor // Numerator, x, 2];
eq1 = a ==
SolveValues[
v == (-a^2 + 2 a c + a^2 c - c^2 - c^3)/(a c - c^2 - c^3),
a][[2]];
eq2 = v == nr;
ContourPlot3D[Evaluate@eq1, {v, 0, 1}, {c, 0, 1}, {a, 0, 1}]
ContourPlot3D[Evaluate@eq2, {v, 0, 1}, {c, 0, 1}, {a, 0, 1}]
Show[%%, %]

Update:
@C.K wanted to see the thickness of the region (see his comment).
The thickness is depicted by slicing the region with planes c=1, c=0.9, ... c=0 for step s=0.1.
The first image is for s=1/10, the second image for s=1/100.
In the code we have to take care of special limit case c=1 - hence the Which and special limit case c=0 - hence the Append.
s = 1/10;
plots = Append[
Table[ContourPlot[
Which[c == 1, {v == (2 - 2 a)/(2 - a), v == 1 - a},
True, {v == (
a^2 - 2 a c - a^2 c + c^2 + c^3)/(-a c + c^2 + c^3),
v == Root[
a^3 - 2 a^2 c - a^3 c + a c^2 + 2 a^2 c^2 -
a c^3 + (-2 a^3 + 5 a^2 c + a^3 c - 4 a c^2 - 2 a^2 c^2 +
c^3 + a c^3) #1 + (a^2 - a^3 - a c - 3 a^2 c + a^3 c +
5 a c^2 - 2 c^3) #1^2 + (-a^2 + a c + a^2 c - 2 a c^2 +
c^3) #1^3 &, 2]}] // Evaluate, {v, 0, 1}, {a, 0, c},
ContourStyle -> Blend[ColorData[97] /@ {1, 4}, c],
PlotPoints -> 50], {c, 1, s, -s}],
ContourPlot[a == 0, {v, 0, 1}, {a, -0.01, 1},
ContourStyle -> Blend[ColorData[97] /@ {1, 4}, 0],
PlotPoints -> 50]];
Show@plots
Manipulate[
Show[plots[[n]], PlotRange -> {0, 1}], {n, 1, Length[plots], 1}]


NIntegrate[ Boole[(-a^2 + 2 a c + a^2 c - c^2 - c^3)/(a c - c^2 - c^3) > v > 1/Root[a^2 - a c - a^2 c + 2 a c^2 - c^3 + (-a^2 + a^3 + a c + 3 a^2 c - a^3 c - 5 a c^2 + 2 c^3) #1 + (2 a^3 - 5 a^2 c - a^3 c + 4 a c^2 + 2 a^2 c^2 - c^3 - a c^3) #1^2 + (-a^3 + 2 a^2 c + a^3 c - a c^2 - 2 a^2 c^2 + a c^3) #1^3 &, 3] && 1 > c > a > 0 && a >= 0], {a, 0, 1}, {c, 0, 1}, {v, 0, 1}, AccuracyGoal -> 6, PrecisionGoal -> 6, Method -> "LocalAdaptive"]results in0.0662847, confirming the set under cosideration is a solid. $\endgroup$