Assume a compact connected manifold $M$ is given. Assume we have a local parametrization $f:U \to M$ such that $M \setminus f(U)$ has zero measure in $M$ and call this property **. Then it is enough to have this single parametrization to calculate the volume of $M$ (example: remove a point from a sphere). While there is the construction of a partition of unity to calculate the volume in case one needs more charts, I think I never saw an example of a calculation where $M$ did not have the property ** and one really had to construct a partition of unity. (Simple textbook examples like spheres, torus etc. all seem to have property **).
So can one classify all such manifolds having property **?